Beilstein J. Org. Chem.2023,19, 317–324, doi:10.3762/bjoc.19.27
imidazoiodaziniums, we show highly delicate post-oxidation functionalizations retaining the hypervalent iodine center.
Keywords: building block; heterocycles; hypervalentcompounds; iodonium salts; one-pot synthesis; Introduction
The chemistry of hypervalent iodine compounds, in particular aryl-λ3-iodanes, is
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Graphical Abstract
Figure 1:
Nitrogen-containing iodolium and iodonium salts.
Beilstein J. Org. Chem.2023,19, 27–32, doi:10.3762/bjoc.19.2
Friedel–Crafts alkylation followed by an anodic oxidative cyclization yielded a defined set of cyclic iodonium salts in a highly substrate-dependent yield.
Keywords: electrochemistry; flow chemistry; hypervalentcompounds; iodine; oxidation; Introduction
Hypervalent iodine compounds (HVI) are well
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Graphical Abstract
Scheme 1:
Synthesis of acyclic (DIS) and cyclic (CDIS) diaryliodonium salts.